Formation Of Vinyl Ethers

Silyl ethers are a group of chemical compounds which contain a silicon atom covalently bonded to an alkoxy group.

Formation of vinyl ethers.

Palladium ii complexes catalyze the formation of enamides via the formal cross coupling reaction between nitrogen nucleophiles and vinyl ethers. 2 2 allyl ether substrates. 8 21 227 228 the mechanism for chain transfer is shown in scheme 9 for the case of α benzyloxystyrene 15 the driving force for fragmentation is provided by formation of a strong carbonyl double bond. A stereospecific and stereoselective copper promoted coupling of vinyl pinacol boronate esters and alcohols allows the synthesis of enol ethers in very good yields is compatible with various functional groups and occurs at room temperature.

The general structure is r 2 c cr or where r h alkyl or aryl a common subfamily of enol ethers are vinyl ethers with the formula roch ch 2 important enol ethers include the reagent 3 4 dihydropyran and the monomers methyl vinyl ether and ethyl vinyl ether. Methyl t butyl ether mtbe is a gasoline additive that boosts the octane number and reduces the amount of nitrogen oxide pollutants. These compounds produce organic peroxides that are significantly less volatile than the solvent in which they are. Molecular structure is the primary factor relating to a material s potential for hazardous peroxide formation.

It is also important that r is a good radical leaving group. 3 1 halide and pseudohalide leaving groups. Glycol ethers decalin and 2 propanol are shown in group b of the previous section. The general structure is r 1 r 2 r 3 si o r 4 where r 4 is an alkyl group or an aryl group.

2 1 vinyl ether substrates. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. 3 2 alkoxide and silyloxide leaving groups. 4 olefination of carbonyl substrates.

In organic chemistry an enol ether is an alkene with an alkoxy substituent. Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. 2 modification of ethers. These vinyl transfer reactions proceed in good yields with amide carbamate and sulfonamide nucleophiles and the optimal catalyst is dpp pd ococf3 2 dpp 4 7 diphenyl 1 10 phenanthroline.

Silyl ether formation may be avoided. Vinyl ethers 1 x ch 2 a o can be very effective addition fragmentation chain transfer agents. Sakurai 177 has found that dicobalt octacarbonyl is an excellent catalyst for the reaction equation 67 and that the side reactions occurring through the use of the catalysts mentioned above e g. Dimethyl ether is used as a spray propellant and refrigerant.

Cupric acetate is the copper source and triethylamine buffer is used to prevent protodeboration.